The organometallic chemistry of N-heterocyclic carbenes /
Huynh, Han Vinh, 1972-
The organometallic chemistry of N-heterocyclic carbenes / Han Vinh Huynh, Department of Chemistry, National University of Singapore. - First edition. - 1 online resource. - Inorganic chemistry : a textbook series .
Includes bibliographical references and index.
Title Page; Table of Contents; Foreword; Preface; List of Abbreviations and Definitions; 1 General Introduction; 1.1 Definition of Carbenes; 1.2 Historical Overview of Carbenes, N‐Heterocyclic Carbenes, and Their Complexes; References; 2 General Properties of Classical NHCs and Their Complexes; 2.1 Stabilization in NHCs (Push‐Pull Effect); 2.2 Backbone Differences and Their Implications; 2.3 Dimerization of Carbenes; 2.4 Nomenclature of N‐Heterocyclic Carbenes; 2.5 Electronic Properties of NHCs and Different Electronic Parameters; 2.6 Steric Properties of NHCs 2.7 Structural Diversity of NHC Ligands and Their ComplexesReferences; 3 Synthetic Aspects; 3.1 General Routes to Azolium Salts as NHC Precursors; 3.2 General Routes to Free NHCs; 3.3 General Synthetic Routes to NHC Complexes; References; 4 Group 10 Metal(0)‐NHC Complexes; 4.1 Nickel(0)‐NHC Complexes; 4.2 Palladium(0)‐NHC Complexes; 4.3 Platinum(0)‐NHC Complexes; References; 5 Group 10 Metal(II)‐NHC Complexes; 5.1 Nickel(II)‐NHC Complexes; 5.2 Palladium(II)‐NHC Complexes; 5.3 Platinum(II)‐NHC Complexes; References; 6 Group 11 Metal‐NHC Complexes; 6.1 Copper(I)‐NHC Complexes 6.2 Silver(I)‐NHC Complexes6.3 Gold(I)‐NHC Complexes; 6.4 Gold(III)‐NHC Complexes; References; 7 Ruthenium, Rhodium, and Iridium Metal‐NHC Complexes; 7.1 Ruthenium(II)‐NHC Complexes; 7.2 Rhodium(I)‐ and Rhodium(III)‐NHC Complexes; 7.3 Iridium(I)‐ and Iridium(III) NHC Complexes; References; 8 Beyond Classical N‐heterocyclic Carbenes I; 8.1 N,S‐Heterocyclic Carbenes (NSHCs); 8.2 N,O‐Heterocyclic Carbenes (NOHCs); 8.3 Expanded Six‐Membered NHCs; 8.4 Expanded Seven‐ and Eight‐Membered NHCs; 8.5 Expanded Diamidocarbenes (DAC); References; 9 Beyond Classical N‐heterocyclic Carbenes II 9.1 Abnormal Imidazolin‐4/5‐ylidenes (aNHC)9.2 Mesoionic 1,2,3‐Triazolin‐5‐ylidenes (MIC); 9.3 Pyrazolin‐3/5‐ylidenes (Pyry) and Indazolin‐3‐ylidenes (Indy); 9.4 Cyclic (Alkyl)(Amino)Carbenes (CAACs) Or Pyrrolidin‐2‐ylidenes; 9.5 Remote N‐Heterocyclic Carbenes (rNHC); References; Index; End User License Agreement
9781118698808 1118698800 9781118698785 1118698789
2016046392
Organometallic chemistry.
Heterocyclic chemistry.
Carbenes (Methylene compounds)
Carbenes (Methylene compounds)
Heterocyclic chemistry.
Organometallic chemistry.
SCIENCE / Chemistry / Organic
Electronic books.
QD411
547/.412
The organometallic chemistry of N-heterocyclic carbenes / Han Vinh Huynh, Department of Chemistry, National University of Singapore. - First edition. - 1 online resource. - Inorganic chemistry : a textbook series .
Includes bibliographical references and index.
Title Page; Table of Contents; Foreword; Preface; List of Abbreviations and Definitions; 1 General Introduction; 1.1 Definition of Carbenes; 1.2 Historical Overview of Carbenes, N‐Heterocyclic Carbenes, and Their Complexes; References; 2 General Properties of Classical NHCs and Their Complexes; 2.1 Stabilization in NHCs (Push‐Pull Effect); 2.2 Backbone Differences and Their Implications; 2.3 Dimerization of Carbenes; 2.4 Nomenclature of N‐Heterocyclic Carbenes; 2.5 Electronic Properties of NHCs and Different Electronic Parameters; 2.6 Steric Properties of NHCs 2.7 Structural Diversity of NHC Ligands and Their ComplexesReferences; 3 Synthetic Aspects; 3.1 General Routes to Azolium Salts as NHC Precursors; 3.2 General Routes to Free NHCs; 3.3 General Synthetic Routes to NHC Complexes; References; 4 Group 10 Metal(0)‐NHC Complexes; 4.1 Nickel(0)‐NHC Complexes; 4.2 Palladium(0)‐NHC Complexes; 4.3 Platinum(0)‐NHC Complexes; References; 5 Group 10 Metal(II)‐NHC Complexes; 5.1 Nickel(II)‐NHC Complexes; 5.2 Palladium(II)‐NHC Complexes; 5.3 Platinum(II)‐NHC Complexes; References; 6 Group 11 Metal‐NHC Complexes; 6.1 Copper(I)‐NHC Complexes 6.2 Silver(I)‐NHC Complexes6.3 Gold(I)‐NHC Complexes; 6.4 Gold(III)‐NHC Complexes; References; 7 Ruthenium, Rhodium, and Iridium Metal‐NHC Complexes; 7.1 Ruthenium(II)‐NHC Complexes; 7.2 Rhodium(I)‐ and Rhodium(III)‐NHC Complexes; 7.3 Iridium(I)‐ and Iridium(III) NHC Complexes; References; 8 Beyond Classical N‐heterocyclic Carbenes I; 8.1 N,S‐Heterocyclic Carbenes (NSHCs); 8.2 N,O‐Heterocyclic Carbenes (NOHCs); 8.3 Expanded Six‐Membered NHCs; 8.4 Expanded Seven‐ and Eight‐Membered NHCs; 8.5 Expanded Diamidocarbenes (DAC); References; 9 Beyond Classical N‐heterocyclic Carbenes II 9.1 Abnormal Imidazolin‐4/5‐ylidenes (aNHC)9.2 Mesoionic 1,2,3‐Triazolin‐5‐ylidenes (MIC); 9.3 Pyrazolin‐3/5‐ylidenes (Pyry) and Indazolin‐3‐ylidenes (Indy); 9.4 Cyclic (Alkyl)(Amino)Carbenes (CAACs) Or Pyrrolidin‐2‐ylidenes; 9.5 Remote N‐Heterocyclic Carbenes (rNHC); References; Index; End User License Agreement
9781118698808 1118698800 9781118698785 1118698789
2016046392
Organometallic chemistry.
Heterocyclic chemistry.
Carbenes (Methylene compounds)
Carbenes (Methylene compounds)
Heterocyclic chemistry.
Organometallic chemistry.
SCIENCE / Chemistry / Organic
Electronic books.
QD411
547/.412