| 000 | 05728cam a2200613Ii 4500 | ||
|---|---|---|---|
| 001 | on1023028384 | ||
| 003 | OCoLC | ||
| 005 | 20201009115353.0 | ||
| 006 | m o d | ||
| 007 | cr cnu|||unuuu | ||
| 008 | 180214s2018 gw ob 001 0 eng d | ||
| 040 |
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| 019 | _a1023486819 | ||
| 020 |
_a9783527674169 _q(electronic bk.) |
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| 020 |
_a3527674160 _q(electronic bk.) |
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| 020 | _a9783527674145 | ||
| 020 | _a3527674144 | ||
| 020 | _z9783527335602 | ||
| 020 | _z3527335609 | ||
| 029 | 1 |
_aCHNEW _b001003129 |
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| 029 | 1 |
_aCHVBK _b516427946 |
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_aGBVCP _b1027307108 |
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| 035 |
_a(OCoLC)1023028384 _z(OCoLC)1023486819 |
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| 050 | 4 | _aQD716.P45 | |
| 072 | 7 |
_aSCI _x013050 _2bisacsh |
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| 082 | 0 | 4 |
_a541/.395 _223 |
| 049 | _aMAIN | ||
| 245 | 0 | 0 |
_aVisible light photocatalysis in organic chemistry / _cedited by Corey R.J. Stephenson, Tehshik P. Yoon, and David W.C. MacMillan. |
| 264 | 1 |
_aWeinheim, Germany : _bWiley-VCH Verlag GmbH & Co., _c[2018] |
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| 300 | _a1 online resource | ||
| 336 |
_atext _btxt _2rdacontent |
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| 337 |
_acomputer _bc _2rdamedia |
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| 338 |
_aonline resource _bcr _2rdacarrier |
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| 504 | _aIncludes bibliographical references and index. | ||
| 520 | _aFilling the need for a ready reference that reflects the vast developments in this field, this book presents everything from fundamentals, applications, various reaction types, and technical applications. Edited by rising stars in the scientific community, the text focuses solely on visible light photocatalysis in the context of organic chemistry. This primarily entails photo-induced electron transfer and energy transfer chemistry sensitized by polypyridyl complexes, yet also includes the use of organic dyes and heterogeneous catalysts. A valuable resource to the synthetic organic community, polymer and medicinal chemists, as well as industry professionals. | ||
| 505 | 0 | _aCover; Title Page; Copyright; Contents; Chapter 1 An Overview of the Physical and Photophysical Properties of [Ru(bpy)3]2+; 1.1 Introduction; 1.2 [Ru(bpy)3]2+: Optical and Electrochemical Properties; 1.2.1 Optical Properties; 1.2.2 Electrochemical Properties; 1.3 Excited State Kinetics; 1.3.1 Steady-State Emission; 1.3.2 Time-Resolved Emission; 1.4 Excited-State Reactivity of [Ru(bpy)3]2+; 1.5 Energy Transfer: FÃœrster and Dexter Mechanisms; 1.6 Electron Transfer; 1.7 Probing the Mechanism, Stage I: Sternâ#x80;#x93;Volmer Quenching Studies. | |
| 505 | 8 | _a1.8 Probing the Mechanism, Stage II: Electron Versus Energy Transfer1.9 Designing Photocatalysts: [Ru(bpy)3]2+ as a Starting Point; 1.10 Conclusion; References; Chapter 2 Visible-Light-Mediated Free Radical Synthesis; 2.1 Introduction; 2.2 Basics of the Photocatalytic Cycle; 2.3 Generation of Radicals; 2.3.1 Formation of C-Centered Radicals; 2.3.1.1 Dehalogenation (I, Br, Cl); 2.3.1.2 Other C-Heteroatom Cleavage; 2.3.1.3 C-C Bond Cleavage; 2.3.2 Formation of N-Centered Radicals; 2.4 C-X Bond Formation; 2.4.1 C-O Bond; 2.4.2 C-N Bond; 2.4.3 C-S and C-Se Bonds; 2.4.4 C-Br Bond; 2.4.5 C-F Bond. | |
| 505 | 8 | _a2.4.6 C-B Bond2.5 C-C Bond Formation; 2.5.1 Formation and Reactivity of Aryl Radicals; 2.5.2 Formation and Reactivity of Trifluoromethyl and Related Radicals; 2.5.2.1 Photocatalyzed Reduction of Perfluorohalogen Derivatives; 2.5.2.2 Photocatalyzed Reduction of Perfluoroalkyl-Substituted Onium Salts; 2.5.2.3 Photocatalyzed Formation of Perfluoroalkyl Radicals from Sulfonyl and Sulfinyl Derivatives; 2.5.3 Formation and Reactivity of Alkyl and Related Radicals; 2.5.3.1 C-C Bond Formation Through Photocatalyzed Reduction of Halogen Derivatives and Analogs. | |
| 505 | 8 | _a2.5.3.2 C-C Bond Formation Through Photocatalyzed Oxidation of Electron-Rich Functional Group2.5.3.3 C-C Bond Formation Through Photocatalyzed Oxidation of Amino Group; 2.6 Radical Cascade Applications; 2.6.1 Intramolecular Polycyclization Processes; 2.6.2 Sequential Inter- and Intramolecular Processes; 2.6.3 Sequential Radical and Polar Processes; References; Chapter 3 Atom Transfer Radical Addition using Photoredox Catalysis; 3.1 Introduction; 3.2 Transition Metal-Catalyzed ATRA; 3.2.1 Ruthenium- and Iridium-Based ATRA; 3.2.1.1 Mechanistic Investigations. | |
| 505 | 8 | _a3.2.1.2 Ruthenium- and Iridium-Based ATRA3.2.2 Copper-Mediated ATRA; 3.2.2.1 Trifluoromethylation; 3.3 Other Photocatalysts for ATRA Transformations; 3.3.1 p-Anisaldehyde; 3.4 Semiconductor; 3.5 Atom Transfer Radical Cyclization (ATRC); 3.6 Atom Transfer Radical Polymerization (ATRP); 3.7 Conclusion; References; Chapter 4 Visible Light Mediated -Amino C-H Functionalization Reactions; 4.1 Introduction; 4.2 Visible Light Mediated -Amino C-H Functionalization Via Iminium Ions; 4.2.1 Aza-Henry Reaction; 4.2.2 Mannich Reaction; 4.2.3 Strecker Reaction; 4.2.4 Friedelâ#x80;#x93;Crafts Reaction. | |
| 588 | 0 | _aVendor-supplied metadata. | |
| 650 | 0 | _aPhotocatalysis. | |
| 650 | 0 | _aChemistry, Organic. | |
| 650 | 7 |
_aSCIENCE _xChemistry _xPhysical & Theoretical. _2bisacsh |
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| 650 | 7 |
_aChemistry, Organic. _2fast _0(OCoLC)fst00853501 |
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| 650 | 7 |
_aPhotocatalysis. _2fast _0(OCoLC)fst01061500 |
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| 655 | 4 | _aElectronic books. | |
| 700 | 1 |
_aStephenson, Corey R. J., _eeditor. |
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| 700 | 1 |
_aYoon, Tehshik Peter, _d1975- _eeditor. |
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| 700 | 1 |
_aMacMillan, David W. C., _eeditor. |
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| 776 | 0 | 8 |
_iPrint version: _tVisible light photocatalysis in organic chemistry. _dWeinheim, Germany : Wiley-VCH Verlag GmbH & Co., [2018] _z3527335609 _z9783527335602 _w(OCoLC)987899028 |
| 856 | 4 | 0 |
_uhttps://doi.org/10.1002/9783527674145 _zWiley Online Library |
| 994 |
_a92 _bDG1 |
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| 999 |
_c79228 _d79228 |
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